WebOct 13, 2014 · The Arrhenius activation parameters for the thermally-induced haptotropic rearrangement were determined: Ea 25.6 ± 1.2 kcal mol−1 and log A 12.5 ± 0.6. View … WebFeb 2, 2015 · Warming induces a haptotropic shift to the neighboring cyclobutadiene rings, followed by the previously reported intercyclobutadiene migration. NMR scrutiny of the primary photoproduct reveals a thermally accessible 16-electron cobalt η 2 -triplet species, which, according to DFT computations, is responsible for the rapid symmetrization of the ...
Investigating pyridazine and phthalazine exchange in a series …
WebThe E isomer of a [5]cumulene derivative, 2,2,9,9-tetramethyl-3,8-diphenyldeca-3,4,5,6,7-pentaene (1), which was previously believed to be unisolable owing to very fast E/Z isomerization, was isolated and structurally characterized. The Z isomer was trapped as the transition-metal complex 5, and the molecular structure was determined. DFT … WebHence, an η 4 → η 2 haptotropic shift of the apical C 8 H 8 ring is calculated to occur during the reduction of 1 to give the dianion [1] 2−. In marked contrast, in complex 4 the haptotropic shift involves the facial, η 8-coordinated cot, which is pushed into an η 6-coordination in the optimized structure of the two-electron reduction ... making hummus recipe
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WebJan 26, 2012 · The second excited state has metal-to-arene charge transfer character and results in a haptotropic shift of the thioanisole ligand. DFT calculations characterized … WebJan 1, 2004 · An experimental and kinetic study of the ethene-bridged complex 3 revealed a haptotropic metal shift onto the adjacent naphthalene ring to give isomer 7 and suggested a competing intermolecular ... Webmetallotropic shift proceeded readily. Examples of such complexes can be found for ruthenium,13 chromium,14 tungsten, platinum11 , 15 16 and rhenium17 metals. In the more recent reports, the 1,2-metallotropic shift has been referred to as a ‘haptotropic shift’ because of the potential to involve a - making hummus with blender